Energy Harvesting in a Bodipy-Functionalized Rotaxane
Journal of Organic Chemistry, cilt.83, sa.21, ss.13228-13232, 2018 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 83 Sayı: 21
- Basım Tarihi: 2018
- Doi Numarası: 10.1021/acs.joc.8b01928
- Dergi Adı: Journal of Organic Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.13228-13232
- Polis Akademisi Adresli: Hayır
Özet
A rotaxane composed of two separate Bodipy-functionalized units can be synthesized with a high yield. The resulting structure shows a very efficient through-space energy transfer (FRET), acting as an energy funnel. Thus, maximum solar output in the visible region can be collected and converted into red light, which can be transformed efficiently with a fine-tuned photovoltaic device. The versatility of the synthetic pathway demonstrates the potential utility of rotaxane-based energy harvesting supramolecules assemblies.